I used this tutorial to install XP64:
Windows XPx64
Insert your Windows XPx64 CD and restart. Go ahead and let rEFIt load up and then choose the Windows CD. Or...when you hear the chime, hold down the C key (to boot from CD).
Windows Setup will start. (Upon initial setup from the Windows CD, the install froze at “checking system hardware”, I was able to get it going again by just touching the power button once, do not press and hold as this will turn off the system)
At the disk partition screen, select the C: drive. "Quick partition" it as NTFS (or FAT32 if you want to write to it in Linux and Mac OS X). Setup will continue and eventually it will restart your computer. (see Talk:Triple_Boot_via_BootCamp for a workaround if the Windows installer does not offer to reformat your windows partition at install time - the Windows installer should format it here or it may not be bootable)
After the first restart, choose the Windows HDD from rEFIt in order to continue setting up XPx64. You will need to repeat this until Windows is fully installed.
Install necessary 64bit drivers specific to the MacPro:
Nvidia drivers for 7300GT graphics card:
http://www.nvidia.com/object/winxp64_93.71.html
Chipset drivers for Intel processor:
http://downloadcenter.intel.com/Detail_ ... n&lang=eng
Network card driver:
http://downloadcenter.intel.com/detail_ ... nldid=8719
Once your internet connection is up, go to Windows update and install the HD audio bus driver before installing the following driver from RealTek:
http://www.realtek.com.tw/downloads/dow ... o%20Codecs
Activate windows: Now that your network card works, activate Windows (so that it doesn't stop working)
You should now have most of your issues in the hardware manager resolved, video up to snuff, and workable audio.
You now have a dual boot system! But obviously, we aren't finished yet.